Nanomechanical behavior and failure mechanisms of …

Montmorillonite, a typical clay mineral, significantly influences the macroscopic deformation and fracture of soft rocks through water absorption-induced swelling and mechanical behavior at …

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Study of a Polyamine Inhibitor Used for Shale …

The shale inhibitor TGA mechanism is mainly to inhibit the hydration expansion of sodium montmorillonite by inhibiting interlayer hydration. The amine group of the inhibitor molecule is dissociated into ammonium cations after hydration and …

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Molecular dynamics simulation of hydration expansion …

Furthermore, the hydration and expansion of VMT may also give rise to complications such as geotechnical instability [13]. ... Influence of inorganic and organic salts …

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Effects of Temperature on Structural Properties of Hydrated

(1) The laboratory results showed that increasing the temperature significantly affected water molecules, and the particle aggregates exhibited inhomogeneous thermal …

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Molecular dynamics study of montmorillonite crystalline swelling…

The larger hydration energy of Ca 2+ ions relative to Na + ions promotes increased water coordination numbers and more pronounced association of water molecules with Ca 2+ …

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Effect of Layer Charge Density on Hydration Properties of

Most researchers believe that montmorillonite with stronger hydration ability layer cations (such as Na +, Li +) has higher expansion and hydrophilicity [21,22,23,24]. On the …

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Insights into the influence mechanism of different interlayer …

They explored the effect of the degree of the hydration of divalent interlayer cations (Mg 2+ /Ca 2+ /Sr 2+ /Ba 2+) on the structure expansion of the interlayer space of …

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DFT study of the adsorption of 2,3

The hydration expansion of montmorillonite is inhibited by 2,3-epoxypropyltrimethylammonium chloride (NW-1 +).The adsorption behaviors of NW-1 + on Na …

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Experimental study on slime water flocculation sediment …

firm whether montmorillonite hydration expansion is restrained or not. 1.2.2 Montmorillonite's single static sedimentation experiment of different electrolyte solutions Take dry 2.5 g …

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Functionality developments in montmorillonite nanosheet: …

The hydration radius of these ions can exceed 0.3 nm [44], contributing further to the hydration expansion of MMT [45]. As the hydration level increases, the interlayer spacing …

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Hydration of bentonite in natural waters: Application of …

A common approach to studying the distinct hydration states of the montmorillonite swelling clays is to vary the conditions of relative humidity and to monitor interlayer expansion …

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Molecular Dynamics Simulation of Clay …

With the increase in temperature, the inhibition of the cations on montmorillonite hydration is weakened, while the effect of pressure is opposite. ... Therefore, fully understanding the mechanism of clay hydration expansion and …

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Imidazolium Gemini ionic liquids for regulating facilely the …

Montmorillonite (Mt) is a ubiquitous swelling clay mineral that exists in sedimentary rocks, surface sediments and soils ... Therefore, after hydration and expansion, the Mt …

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Mechanisms of hydration inhibition on the surface of montmorillonite …

Borehole instability is one of the most complicated technical problems in oil and gas exploration and development.The hydration and expansion of clay minerals is the critical factor causing …

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Effects of Salinity on Formation Behavior of …

The hydration expansion of montmorillonite is ma inly affected by the surface . hydration force, osmotic hydration force and capill ary force. In addition, the water adsorbed by .

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Study of hydration of kaolinite and montmorillonite mixture by …

Specific features of the hydration process of the sodium form of montmorillonite were investigated by the DFT method in [28]. It has been found that the energies of water …

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Molecular Simulation of Hydration Characteristics of …

By comparing and analyzing the data in Table 1, it can be found that under different hydration conditions, each inhibitor has a different degree of inhibition of sodium …

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Nanomechanical behavior and failure mechanisms of …

The interlayer cations in montmorillonite gradually undergo hydration with water molecules entering the layers, diminishing the interaction forces that contact the cations with the surfaces …

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Insights into the influence mechanism of different interlayer …

In this study, the adsorption behavior and hydration mechanism of water molecules on the surface of four cationic forms of montmorillonites (Li Mt, Na Mt, K Mt, and Ca Mt) were …

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Swelling of Montmorillonite from Molecular Simulations: …

The RH of hydration transition strongly depends on the nature of the clay, in particular the layer charge and its localization in the mineral layers (surface vs. center), and on the nature of the …

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Composite Hydration Process of Clay Minerals …

In fact, the hydration of montmorillonite is more intense compared with illite, that is, the presence of montmorillonite has a more serious effect on the expansion of clay minerals. 4.4. Effect of Cations on the Hydration of Clay …

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Influence of inorganic and organic salts on the hydration …

Huang et al. 11 investigated the mechanism of inhibiting the hydration of montmorillonite by small organic amine molecules, and found that formamide has a better …

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Molecular dynamics simulation of sodium montmorillonite …

With the increase of burial depth and interlayer water content, the volume of sodium montmorillonite increases, while the density decreases correspondingly. The increase of …

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Experimental study on the damage of organic-rich shale …

The hydration expansion stress and strain tester, which was developed based on the principle of the fixed-volume method, is used to evaluate the hydration expansion strain …

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(PDF) Molecular Dynamics Simulation of Clay …

Hydration swelling and the interlayer structure properties of Na-montmorillonite were modeled with the energy minimizing and molecular dynamics (MD) module of Cerius2.

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Expansion characteristics of organo montmorillonites during …

Expansion characteristics of organo montmorillonites during the intercalation, aging, drying and rehydration processes: Effect of surfactant/CEC ratio ... Although sydration …

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Molecular dynamics simulation of hydration expansion …

The expansive clay minerals are mainly montmorillonite (MMT) and vermiculite (VMT), which are known for their interlayer hydration and swelling [8]. Studies on the swelling …

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Hydration-induced damage of tight conglomerates

It is widely recognized that the primary factors contributing to hydration-induced damage in conglomerate reservoirs in the Junggar Basin include montmorillonite water …

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Molecular Simulation of Hydration Characteristics of Montmorillonite …

By comparing and analyzing the data in Table 1, it can be found that under different hydration conditions, each inhibitor has a different degree of inhibition of sodium …

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Systematic comparison of the hydration and dehydration of …

A number of studies have examined the hydration behaviors of montmorillonite with Na + and K +; however, assessments of smectite species other than montmorillonite, the …

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